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Prince Carlos, Duke of Parma and Piacenza (Carlos Xavier Bernardo Sixto Marie; born 27 January 1970) is the current Head of the House of Bourbon-Parma, which ruled the Duchy of Parma and Piacenza from 1748 to 1802 and from 1847 to 1859. He assumed the role upon the death of his father in 2010.

The eldest son of Carlos Hugo, Duke of Parma and Princess Irene of the Netherlands, Carlos is also a member of the Dutch royal family and the Dutch nobility with the style of "His Royal Highness" and the title of Prince Carlos de Bourbon de Parme. Additionally, he is the Carlist pretender to the Spanish throne with the title Duke of Madrid. In the French nobility, he bears the title "Prince de Borbon", and is the grand master of the Parmesan Sacred Military Constantinian Order of Saint George, the Order of Saint Louis for Civil Merit, the Order of Prohibited Legitimacy and the Order of St. George for Military Merit.

Princess Annemarie of Bourbon-Parma, Duchess of Parma and Piacenza (née Gualthérie van Weezel; born 18 December 1977) is a Dutch consultant, former journalist, and a member of the House of Bourbon-Parma and the Dutch royal family. She worked as a television journalist, specializing in European politics, for the Dutch station NOS Journaal. In 2011, she authored the book De smaak van macht, which focused on the lives of five former Dutch prime ministers. In 2019, Annemarie left journalism and became the first woman to make partner at the consulting firm Ward Howell International.

She is married to Prince Carlos, Duke of Parma, the pretender to the defunct throne of the extinct Duchy of Parma and Piacenza and the Carlist claimant to the Spanish throne. As such, Annemarie is considered the Spanish queen by Carlists. She is the Countess of Molina in her own right, having been bestowed with the title by her father-in-law, Carlos Hugo, Duke of Parma, in 2010. Per a 1996 royal decree issued by Queen Beatrix of the Netherlands, upon her marriage she became entitled to the style and title Her Royal Highness Princess Annemarie de Bourbon de Parme in the Netherlands as a member of the extended royal family.